Dithiooxalate
WebAbstract A series of crystalline salts based on the [M (dto) 2] 2− (dto = 1,2-dithiooxalate, M = Ni, Pt, Cu) dianion with hydrogen-bond donor cations have been synthesised following a molecular tectonics approach. The chelating M (dto)⋯HN supramolecular synthon has been exploited in a systematic study of its robustness. WebOct 1, 1997 · Metal-organic ion-pair charge-transfer complexes of the general formula {A 2+ [ML 2] 2− }, of which [ML 2] 2− is a planar metal dithiolene, M=Ni, Pd, Pt, Co, Cu Zn, and A 2+ =2,2′- or 4,4′-bipyridinium compound, were investigated in …
Dithiooxalate
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WebPlatinum dithiooxalate C2H2O2PtS2 CID 137231926 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological ... WebThe chelating dithiooxalate–HN interaction is a robust and reliable synthon even in the presence of alternative donors and acceptors. The carbonyl functions are also potent hydrogen bond acceptors in the plane of the anion. This article is …
WebShort-term effects may include irritation to the eyes, pupil constriction and blurring of vision, abdominal cramps, laboured breathing, nausea, vomiting, diarrhoea, muscle cramps and … WebJul 17, 2002 · The use of NH⋯XM (X = Cl, Br) supramolecular synthons based on anionic perhalometallate hydrogen bond acceptors and cationic, usually pyridinium, N–H donors has previously allowed controlled crystal synthesis. The use of different molecular tectons (building blocks) with new but analogous synthons to generate a more diverse range of …
WebA series of crystalline salts based on the complex dianion [Fe(dto)2(NO)]2− (dto = 1,2-dithiooxalate) with hydrogen-bond donor cations have been synthesised. The preparation and structural characterisation of the new crystalline phases [4,4′-H2bipy][Fe(dto)2(NO)]·H2O (1), [3,3′-H2bipy][Fe(dto)2(NO)] (2) and … WebMar 13, 1996 · Chiral, Three-Dimensional Supramolecular Compounds: Homo- and Bimetallic Oxalate- and 1,2-Dithiooxalate-Bridged Networks. A Structural and …
WebConsider the dithiooxalate ion, C 2 S 2 O 2 2-. It looks like an oxalate ion where each carbon atom has one C-O and one C-S bond (as well as a C-C bond, obviously!). Like the oxalate ion, it can act as a bidentate ligand when it binds to a metal ion. Draw the most likely way for the ion to bind to (A) a platinum(II) ion and (B) a nickel(II) ion.
WebThe complex [1- (4′-fluorobenzyl)pyridinium]2 [Ni (dto) 2] (dto2- means clithiooxalate dianion) has been prepared by reaction of Na2 [Ni (S2C2O2) 2] and the 1- (4′-fluorobenzyl) pyridinium chloride... marymount clinical counselingWebFeb 25, 2002 · Abstract. Dimethyltin dithiooxalate has been synthesised by the reaction of dimethyltin dichloride with potassium dithiooxalate. It may be used as a dithiooxalate (dto) transfer reagent, reacting with (PtL 2 Cl 2 ) (L 2 = 1,4-cyclooctadiene or 4,4′-bis( tert -butyl)-2,2′-bipyridine) to eliminate SnMe 2 Cl 2 and form the corresponding platinum … marymount cleveland hospitalWebAug 1, 2011 · The insertion of sulfur into a dithiocarboxylic group of O-methyl-1,1-dithiooxalate with formation of a perthiooxalate ligand can be observed by 13C NMR. A series of perthiooxalate mixed-ligand ... hustle cafe harrogateWebThis article is cited by 22 publications. Akram Hijazi, Justin Claude Kemmegne-Mbouguen, Sébastien Floquet, Jérôme Marrot, Cédric R. Mayer, Vincent Artero, and Emmanuel Cadot . hustle canvas wall artWebBiacetyldihydrazone (BdH) complexes [M(BdH)3](NO3)2 (M=CoII, NiII, CuII or ZnII); [Fe(BdH)3](NO3)3; [M(BdH)3][Ni(dto)2] (M=CoII, NiII or ZnII; dto=dithiooxalate); [Cu(BdH)2][Ni(dto)2] and [Fe(BdH)3]2[Ni(dto)2]3 have been prepared and characterized by chemical analysis, conductance measurements, electronic and i.r. spectral studies and … hustle canvas artWebElectronic spectra, electrochemistry, and SCF-X.alpha.-DV calculations for bis (phosphine)palladium oxalate and dithiooxalate complexes. Crystal and molecular structures of (dithiooxalato-S,S')bis (trimethylphosphine)palladium (II) and (1,1-dithiooxalato-S,S')bis (.mu.3-sulfido)-2,2,3,3-tetrakis (trimethylphosphine)-triangulo-tripalladium (II) hustle cafe facebookWebThe mto ligand chelates to the Mo atom through one oxygen atom and the sulfur atom. The two Cp rings form dihedral angles of 24° with the least-squares plane of the mto ligand. The Mo−O and Mo−S bond distances are 2.193 (5) and 2.449 (2) Å, respectively. Download to read the full article text References Dieztsch, W.; Strauch, P.; Hoyer, E. Coord. hustle cafe